Designed Polymers for Water Purification and Clean Energy Generation
Reversible Capture and Release of Hg(II) from Water Using Conducting Polymers
Heavy metal ions, especially mercury (Hg) in water, are highly toxic, so become a threat to public health and environment. In this work, I demonstrated how the redox active polyaniline reversibly captured and released Hg(II) in water. Polyaniline naturally adsorbs Hg(II), and subsequent dose of oxidation potential induces the release. Nanofiber geometry of polyaniline offered faster adsorption kinetics, and additional sulfur chelating groups enhanced uptake capacity.
Current work targets different toxic ions with higher capacity and faster response.
Highly Stable and Conducting Anion Exchange Membranes for Fuel Cells
Anion exchange membrane fuel cells are a clean and efficient promising future energy source. However, the development of stable high-performance membranes remains a major challenge. Herein I demonstrated how the effective phase separation improved both chemical and mechanical properties of the membranes.
Current work focuses on design and synthesis of new cations and new polymers to overcome the above mentioned challenges.
Science and Engineering on Nanocomposites
Stretchable Nanoparticle Conductors
Excellent stretchable conductors from self-organization of nanoparticles (NPs) are demonstrated. Free-standing stretchable conductors were prepared by layer-by-layer (LBL) assembly. High conductivity and stretchability originated from dynamic self-organization of NPs. Modified percolation theory to incorporate the self-organization supports the experimental observation.
Reconfigurable Chiroptical Nanocomposites
Chiroptical nanocomposites for the applications of metamaterials devices and optoelectronics are demonstrated. Nanocomposites were LBL assembled from NPs or single-walled carbon nanotubes. Chiroptical activities were reversibly tunable by macroscale stresses. S-like non-planar nano-assemblies are responsible for the optical activities and this was confirmed by computational simulations.
Cross-linked Porous Networks
Porous materials are widely used for chemical separations, sensing, and storage. Highly porous (surface areas up to 1,200 m g-1) and robust materials using octaphenylsilsesquioxanes are synthesized. Copper-mediated in-situ homocoupling effectively constructed the networks.